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Download Analytical Applications of EDTA and Related Compounds by R. Přibil, R. Belcher, H. Freiser PDF

By R. Přibil, R. Belcher, H. Freiser

Analytical purposes of EDTA and similar Compounds examines the analytical purposes of ethylenediaminetetra-acetic acid (EDTA) and similar compounds. This publication additionally considers the “passive” function of those components, that's, their screening (masking) homes, which drastically enhance the selectivity of the reactions in universal use.
This textual content involves six chapters geared up into sections. the 1st half offers with the makes use of of EDTA and its derivatives in a few fields of chemical research. After offering an outline of the historical past at the back of the advance of EDTA as an analytical reagent, this e-book discusses to the character of equilibria of complexes and the equipment utilized in their research. the subsequent bankruptcy is devoted to the reactions of “classical” gravimetric research, together with the precipitation reactions by way of natural reagents. The bankruptcy on colorimetry incorporates a part on “colored complexing agents,” that are used additionally in colorimetric determinations of a few components. this article concludes by way of comparing using EDTA as a protecting agent in colorimetry.
This publication may be of curiosity to scholars and practitioners operating in analytical chemistry and similar disciplines, together with polarography, chromatography, electrophoresis, flame photometry, and qualitative research.

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Extra resources for Analytical Applications of EDTA and Related Compounds

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COOH and by the isomers of D C T A (p. 4 1 , formulae I, II, III). An increase of 72 above 2, and the increased separation of ligands in the case of acids II and III, greatly reduced the stability of M Y ^ " complexes; the stability of the M H Y " com­ plex is defined as KMHY = [MHY]/[M] [HY] and remains practically the same, at least with alkaline earth metals (see Table XIV). A value of η greater than or equal to 4 will also give rise t o an M2Y complex. e. tetramethylenediamine tetra-acetic acid ( T M D T A ) is only a tridentate complex former.

Am. Chem. Soc. 7 4 , 1 4 5 2 ( 1 9 5 2 ) . BLUMER, M . and KOLTHOFF, I . , Experientia 8 , 1 3 8 ( 1 9 5 2 ) . PECSOK, R . L . and MAVERICK, E . F . , Τ. Am. Chem. Soc. 7 6 , 3 5 8 ( 1 9 5 4 ) . PECSOK, R . L . and JUVET, R . , / . Am. Chem. Soc. 7 5 , 1 2 0 2 ( 1 9 5 3 ) . 5 9 . MiCKA, K . and TOCKSTEIN, Α . , Chem. listy 4 8 , 6 4 8 ( 1 9 5 4 ) . 6 0 . ECKARDT, D . and HOLLECK, L . , Z . Elektrochem. 5 9 , 2 0 2 (1955). 6 1 . MATYSKA, B . and KÖSSLER, L , Chem. listy 4 5 , 2 5 4 ( 1 9 5 1 ) ; Coll.

The result is a large reduction of free metal ion concentration and a displace­ ment of the equilibrium H3tren^+ + M Y ^ - + M'^^ ^ Mtren^+ + Μ Ύ ^ - + 3 H+ (I) to the right during titration. Suitable M'^"^ ions were those alkaline earth metals which did not form complexes with trisaminotriethylamine. The lanthanum ion was also suitable. The equihbrium constant of equation (I) could then be determined from the titration curve, and from the stability constant . 55) Using this method, one must take into account the slow estabhshment of the displace­ ment equilibrium (I).

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